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Title: | Inhibition effect of adsorption layer of 1-phenyl-4-(4-nitrophenyl) thiosemicarbazide on the corrosion of 18 Ni 250-grade welded maraging steel in 1.0 M hydrochloric acid medium |
Authors: | Kumar, P. Nityananda, Shetty, A. |
Issue Date: | 2015 |
Citation: | Research on Chemical Intermediates, 2015, Vol.41, 10, pp.7095-7113 |
Abstract: | The thiosemicarbazide derivative, 1-phenyl-4-(4-nitrophenyl)thiosemicarbazide (PNPT), was synthesized and its inhibiting action on the corrosion of welded maraging steel in 1.0 M hydrochloric acid was investigated by electrochemical methods of potentiodynamic (Tafel) polarization and electrochemical impedance spectroscopy. The inhibitor, PNPT, acted essentially as a mixed-type inhibitor with predominant cathodic action. The inhibition efficiency increased with the increase in inhibitor concentration. An inhibition efficiency of about 86 % was exhibited at 30 C, which decreased with the increase in the temperature. The adsorption of the inhibitor layer formed was through predominant physical adsorption process. 2014 Springer Science+Business Media Dordrecht. |
URI: | http://idr.nitk.ac.in/jspui/handle/123456789/11709 |
Appears in Collections: | 1. Journal Articles |
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