Single-step oxidative homocoupling of aryl Grignard reagents via Co(II), Ni(II) and Cu(II) Complexes under air

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DC Field	Value	Language
dc.contributor.author	Bhat, A.P.I.
dc.contributor.author	Bhat, B.R.
dc.date.accessioned	2020-03-31T08:45:59Z	-
dc.date.available	2020-03-31T08:45:59Z	-
dc.date.issued	2014
dc.identifier.citation	Applied Organometallic Chemistry, 2014, Vol.28, 6, pp.383-388	en_US
dc.identifier.uri	http://idr.nitk.ac.in/jspui/handle/123456789/13479	-
dc.description.abstract	A simple catalytic system of direct synthesis for the symmetrical biaryls using catalytic amounts of Co(II), Ni(II) and Cu(II) complexes has been developed. The reaction system involves in situ synthesis of Grignard reagents. The complexes, containing bidentate Schiff base and dmit (2-thioxo-1,3-dithiole- 4,5-dithiolate) ligands, were compatible with diverse functionalities and afford a high yield of biaryls in a single step, proving to be promising catalysts in homocoupling reactions. Atmospheric oxygen is used as an oxidant which renders a green, simple and economical catalytic route. Copyright 2014 John Wiley & Sons, Ltd.	en_US
dc.title	Single-step oxidative homocoupling of aryl Grignard reagents via Co(II), Ni(II) and Cu(II) Complexes under air	en_US
dc.type	Article	en_US
Appears in Collections:	1. Journal Articles

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