Please use this identifier to cite or link to this item: https://idr.l2.nitk.ac.in/jspui/handle/123456789/13299
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dc.contributor.authorMurthy, Y.L.N.
dc.contributor.authorSuhasini, K.P.
dc.contributor.authorVeeraiah, V.
dc.contributor.authorUmesh, G.
dc.contributor.authorManjunatha, K.B.
dc.contributor.authorChristopher, V.
dc.date.accessioned2020-03-31T08:45:33Z-
dc.date.available2020-03-31T08:45:33Z-
dc.date.issued2013
dc.identifier.citationDyes and Pigments, 2013, Vol.99, 3, pp.713-719en_US
dc.identifier.urihttp://idr.nitk.ac.in/jspui/handle/123456789/13299-
dc.description.abstractFive new 4-substituted arylidene-2-[5-(2,6-dichlorophenyl)-3-methyl-1,2- oxazol-4-yl]-1,3-oxazol-5-ones have been designed and synthesized in order to study their third-order nonlinear optical properties. These novel compounds were characterized by advanced spectroscopic techniques (IR, 1H, 13C NMR, ESI-MS spectroscopy and elemental analyses). In addition, the evaluation of absorption and emission wavelengths of the new 5-oxazolone derivatives was carried out in seven different solvents of varying polarity, which showed intense absorption maxima at 350-480 nm and emission maxima at 390-535 nm respectively. The third-order nonlinear optical properties of the target molecules have been investigated in N,N-dimethylformamide using a single beam Z-scan technique with nanosecond laser pulses at 532 nm. The nonlinear refractive index, nonlinear absorption coefficient, magnitude of third-order susceptibility and molecular two photon absorption cross-sections have been determined. All of the compounds showed excellent optical limiting behaviour at 532 nm, with the best optical limiting behaviour observed with strong electron donor [dimethyl and N,N-diethyl amino] substituents. 2013 Elsevier Ltd. All rights reserved.en_US
dc.titleSynthesis, characterization and evaluation of the photophysical and nonlinear optical behaviour of novel 4-substituted arylidene-2-[5-(2,6- dichlorophenyl)-3-methyl-1,2-oxazol-4-yl]-1,3-oxazol-5-onesen_US
dc.typeArticleen_US
Appears in Collections:1. Journal Articles

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