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dc.contributor.authorDhara, B.
dc.contributor.authorTarafder, K.
dc.contributor.authorJha, P.K.
dc.contributor.authorPanja, S.N.
dc.contributor.authorNair, S.
dc.contributor.authorOppeneer, P.M.
dc.contributor.authorBallav, N.
dc.date.accessioned2020-03-31T08:41:51Z-
dc.date.available2020-03-31T08:41:51Z-
dc.date.issued2016
dc.identifier.citationJournal of Physical Chemistry Letters, 2016, Vol.7, 24, pp.4988-4995en_US
dc.identifier.urihttp://idr.nitk.ac.in/jspui/handle/123456789/12584-
dc.description.abstractOwing to long spin-relaxation time and chemically customizable physical properties, molecule-based semiconductor materials like metal-phthalocyanines offer promising alternatives to conventional dilute magnetic semiconductors/oxides (DMSs/DMOs) to achieve room-temperature (RT) ferromagnetism. However, air-stable molecule-based materials exhibiting both semiconductivity and magnetic-order at RT have so far remained elusive. We present here the concept of supramolecular arrangement to accomplish possibly RT ferromagnetism. Specifically, we observe a clear hysteresis-loop (Hc ? 120 Oe) at 300 K in the magnetization versus field (M-H) plot of the self-assembled ensembles of diamagnetic Zn-phthalocyanine having peripheral F atoms (ZnFPc; S = 0) and paramagnetic Fe-phthalocyanine having peripehral H atoms (FePc; S = 1). Tauc plot of the self-assembled FePc ZnFPc ensembles showed an optical band gap of ?1.05 eV and temperature-dependent current-voltage (I-V) studies suggest semiconducting characteristics in the material. Using DFT+U quantum-chemical calculations, we reveal the origin of such unusual ferromagnetic exchange-interaction in the supramolecular FePc ZnFPc system. 2016 American Chemical Society.en_US
dc.titlePossible Room-Temperature Ferromagnetism in Self-Assembled Ensembles of Paramagnetic and Diamagnetic Molecular Semiconductorsen_US
dc.typeArticleen_US
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